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81.
摘 要 为研究甘肃地区松针中无机元素的含量,探究不同品种松针中无机元素的差异,采用HNO3(65%)对松针样品进行微波消解,电感耦合等离子体质谱(ICP-MS)法测定甘肃两地区6种松针中28种无机元素的含量,结合主成分分析以及偏最小二乘判别分析对松针地区差异进行判别;结果显示松针中无机元素含量丰富,其中Na、Mg、Al、K、Ca、Fe、Zn、Mn、Sr等元素在不同品种松针中均有较高含量,主成分分析结果显示共有7个主成分,累积贡献率达到92.58%,偏最小二乘判别分析显示两地区6种松针在地区上可被明显分开,其中Mg、Fe、Zn、Mn、Sr、K 6种元素为造成地区差异的主要元素。实验结果表明松针中元素种类丰富,人体必需微量元素含量较高,且不同地区松针在地区上具有一定的一致性和特异性。 相似文献
82.
Baohuai Sheng 《分析论及其应用》2006,22(4):319-328
In the present paper,we provide a way of constructing translation network operators by Bernstein-Durrmeyer operators. 相似文献
83.
G. A. Dzyubenko 《分析论及其应用》2006,22(3):233-245
Let a function f ∈ C[-1, 1], changes its monotonisity at the finite collection Y := {y1,… ,ys} of s points yi ∈ (-1, 1). For each n ≥ N(Y), we construct an algebraic polynomial Pn, of degree ≤ n, which is comonotone with f, that is changes its monotonisity at the same points yi as f, and |f(x)-Pn(x)|≤c(s)ω2(f,(√1-x2)/n), x∈[-1,1],where N(Y) is a constant depending only on Y, c(s) is a constant depending only on s and ω2 (f, t) is the second modulus of smoothness of f. 相似文献
84.
A fast, simple and costless methodology without sample pre-treatment is proposed for the discrimination of beers. It is based on cyclic voltammetry (CV) using commercial carbon screen-printed electrodes (SPCE) and includes a correction of the signals measured with different SPCE units. Data are submitted to partial least squares discriminant analysis (PLS−DA) and support vector machine discriminant analysis (SVM−DA), which allow a reasonable classification of the beers. Also, CV data from beers can be used to predict their alcoholic degree by partial least squares (PLS) and artificial neural networks (ANN). In general, non-linear methods provide better results than linear ones. 相似文献
85.
Prof. Dr. Muhammet Erkan Köse 《Chemphyschem》2021,22(20):2078-2092
Excited state geometries of molecules can be calculated with highly reliable wavefunction schemes. Most of such schemes, however, are applicable to small molecules and can hardly be viewed as error-free for excited state geometries. In this study, a theoretical approach is presented in which the excited state geometries of molecules can be predicted by using vibrationally resolved experimental absorption spectrum in combination with the theoretical modelling of vibrational pattern based on Franck-Condon approximation. Huang-Rhys factors have been empirically determined and used as input for revealing the structural changes occurring between the ground and the excited state geometries upon photoexcitation. Naphthalene molecule has been chosen as a test case to show the robustness of the proposed theoretical approach. Predicted 1B2u excited state geometry of the naphthalene has similar but slightly different bond length alternation pattern when compared with the geometries calculated with CIS, B3LYP, and CC2 methods. Excited state geometries of perylene and pyrene molecules are also determined with the presented theoretical approach. This powerful method can be applied to other molecules and specifically to relatively large molecules rather easily as long as vibrationally resolved experimental spectra are available to use. 相似文献
86.
A direct, reagent-free, ultraviolet spectroscopic method for the simultaneous determination of nitrate (NO3−), nitrite (NO2−), and salinity in seawater is presented. The method is based on measuring the absorption spectra of the raw seawater range of 200–300 nm, combined with partial least squares (PLS) regression for resolving the spectral overlapping of NO3−, NO2−, and sea salt (or salinity). The interference from chromophoric dissolved organic matter (CDOM) UV absorbance was reduced according to its exponential relationship between 275 and 295 nm. The results of the cross-validation of calibration and the prediction sets were used to select the number of factors (4 for NO3−, NO2−, and salinity) and to optimize the wavelength range (215–240 nm) with a 1 nm wavelength interval. The linear relationship between the predicted and the actual values of NO3−, NO2−, salinity, and the recovery of spiked water samples suggest that the proposed PLS model can be a valuable alternative method to the wet chemical methods. Due to its simplicity and fast response, the proposed PLS model can be used as an algorithm for building nitrate and nitrite sensors. The comparison study of PLS and a classic least squares (CLS) model shows both PLS and CLS can give satisfactory results for predicting NO3− and salinity. However, for NO2− in some samples, PLS is superior to CLS, which may be due to the interference from unknown substances not included in the CLS algorithm. The proposed method was applied to the analysis of NO3−, NO2−, and salinity in the Changjiang (Yangtze River) estuary water samples and the results are comparable with that determined by the colorimetric Griess assay. 相似文献
87.
88.
89.
低场核磁共振结合化学计量学方法快速检测掺假核桃油 总被引:4,自引:0,他引:4
以掺假核桃油样品为低场核磁共振检测对象,利用主成分分析法(PCA)和偏最小二乘回归法(PLSR)分析处理Carr-Purcell-Meiboom-Gill(CPMG)序列的核磁共振弛豫数据,旨在探求一种能快速检测核桃油品质的新方法。对几种常见掺假形式(掺入大豆油、玉米油、葵花油)的核桃油样品和纯核桃油样品进行检测和评价。实验结果表明:纯核桃油和掺入不同种类食用油的掺假核桃油在主成分得分图上可以得到很好的区分,且掺假样品随掺假比例在图中呈规律性分布;采用PLSR法对CPMG数据和实际掺假率进行回归,可实现对核桃油掺假水平的准确定量测定。方法快速、无损、准确,在食用油制品的品质控制及评价方面具有很大的应用潜力。 相似文献
90.
LiuShutian 《Acta Mechanica Solida Sinica》2004,17(2):150-157
I. INTRODUCTION Reliability analysis is becoming increasingly important in structural design. Over the years, manyresearchers have been involved in the evaluation of failure probability and many methods have beenpresented for structural reliability anal… 相似文献